Halogenated acetylene compounds are unstable and should be treated as explosives. Even the presence of sodium chloride changes a mixture of non-halogenated solvents into halogencontaining solvent waste. Material' and further information such as 'Halogenated Solvents', or 'Cyanides'. Solvents are normally collected in 2.5 litre or 5 litre bottles in laboratories. The addition was prompted by petitions to list 1-BP by the Halogenated Solvents Industry Alliance and the New York State Department of Environmental Conservation. F List of Hazardous Waste • w-hw2-00 • January 2011 page 2 Explanation of F List Reason for listing Each group of wastes on the F List (list) was included for one or more of the following reasons, identified in the list by the . A chemical waste is a hazardous waste due to corrosivity if: It is aqueous and has a pH less than or equal to 2, or greater than or equal to 12.5, or. identifies the constituent which caused EPA to list the waste in §261.31 or §261.32 as EP toxic or toxic waste. VEHS Quick Facts: • Store hazardous waste in sealed, compatible containers. Dangerous Waste Sources List Non-Specific Sources "F" List Dangerous Waste No. Hazard code. Waste halogenated or unhalogenated non-aqueous distillation . Other aqueous waste or wastewaters (fluid but not sludge) W117. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. These include "acutely hazardous" wastes such as arsenic acid, cyanides, and many pesticides, as well as "toxic" wast es such as benzene, toluene, and phenols. In Appendix VII, only the listed solvents are specified. to keep the halogen content of the organic solvents for incineration below 1.0% by volume. LIST OF TOXIC INDUSTRIAL WASTE COLLECTORS non-chlorinated) solvent w204 concentrated halogenated / non-halogenated solvent mixture w205 oil-water emulsion or mixture w206 waste oil managed as hazardous waste w209 paint, ink, lacquer, or varnish w210 reactive or polymerizable organic . Do not dispose of organic solvents down the drain. Guidelines for handling hazardous waste other than . Spent Non-Halogenated solvent Acetone, methanol, solvent R150, xylene, toluene, Generators of organic solvents should keep non-halogenated waste solvents separated from halogenated waste solvents to the fullest extent possible. waste code waste description; d000: description: d001: ignitable waste: d002: corrosive waste: d003: reactive waste: f002: the following spent halogenated solvents: tetrachloroethylene, methylene chloride, trichloroethylene, 1,1,1-trichloroethane, chlorobenzene, 1,1,2-trichloro-1,2,2-trifluoroethane, ortho-dichlorobenzene, trichlorofluoromethane, and 1,1,2 . Waste non-halogenated organic solvents but excluding such wastes specified on list B. A3150. Waste chemicals should not be discarded as General Waste or as Biological Waste and not be poured down the sink drains. There is no difference if the waste contains halogenated solvents or if halogenfree solvents are contaminated with halogen-containing reagents. Halogenated Chloroform L Dichloromethane L Other Flammable Solvents Please list any other solvents below Other Information For office use only Gallons: Pounds: Tips on Keeping Accurate Inventory of Carboy Content • Put one person in charge of waste solvent collection and record keeping. F004 The following spent non-halogenated solvents: Cresols and cresylic acid, and nitrobenzene; all spent solvent mixtures/blends Chemical wastes can be collected in several different types of containers for disposal. The rule regulates the emissions of the following halogenated hazardous air pollutants (HAP) solvents: methylene chloride (MC), perchloroethylene (PCE), trichloroethylene (TCE), 1,1,1- trichloroethane (TCA), carbon tetrachloride (CT), and chloroform (C). However, many halogenated organic compounds of high molecular weight, in particular those containing several halogen atoms per molecule, are nonflammable; some are in fact used as fire retardants. Chloroform 10. the following spent halogenated solvents used in degreasing: tetrachloroethylene, trichlorethylene, methylene chloride, 1,1,1-trichloroethane, carbon tetrachloride and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume) of one or more of the above . u res However, regardless of the brand name or the proprietary formulation of a solvent, it typically falls into one of three categories of cleaning solvents: oxygenated solvents, hydrocarbon solvents, or . REACH has no secondary waste streams, uses an environmentally benign solvent, and aims to catalytically destroy rather than transfer the organic contaminants into a different phase. Hazardous chemical waste may include oils, solvent waste, reaction by-products, washings, chemicals that are obsolete / out of date chemicals, water treatment chemicals, biocides, unknown substances and novel compounds. Examples include halogenated solvents, nonhalogenated solvents, electroplating sludges, and cyanide solutions from plating batches. Halogenated solvents include methylene chloride and chloroform. The following spent non-halogenated solvents: Cresois and cresylic acid, and Nitrobenzene; all spent solvent mixtures/blends containing, before use, a total of ten percent or more (by volume) of one or more of the above non-halogenated solvents or those solvents listed in F001, F002, and 2. 5.2 Listed Hazardous Waste The four lists of hazardous waste include the following which in total includes over 800 different substances. Halogenated Solvent Waste: Solvent waste that contains, either in total or as a mixture, halogenated solvents such as chloroform, dichloromethane (methylene chloride) Industry and EPA hazardous waste No. 5. Bromodichloromethane 2. •p Keep a clipboard with this form nearby. Industry and EPA hazardous waste No. Sources F001 The following spent halogenated solvents used in degreasing: Tetrachloroethylene, trichloroethylene, methylene chloride, 1,1,1-trichloroethane, carbon tetrachloride, and chlorinated fluorocarbons; all spent solvent The term "halogen" means they are all in the same column on the periodic table of the elements (if you're interested, see col. 17 on the right-hand side of the table). solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume) of one or more of the above halogenated solvents or those solvents listed in F002, F004, and F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. Hazardous Waste Number Source; F001: The following spent halogenated solvents used in degreasing: Tetrachloroethylene, trichloroethylene, methylene chloride, 1,1,1-trichloroethane, carbon tetrachloride, and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume) of one or more of the above halogenated . The halogenated wastes must be incinerated specifically for destruction at 99.99% level (i.e., to carbon dioxide, water and hydrogen chloride) with scrubbing for hydrogen chloride, which is a more costly waste stream. Caustic aqueous waste without cyanides (pH >12.5) W113. Maintain a completed , up-to-date, waste manifest form with the waste container while in the lab. Each bottle must display the appropriate label which can be obtained from your local Health and Safety co-ordinator. The flammability of these materials is variable. 1,2-Dibromomethane 14. Halogenated solvents routinely used at the PSFC include: - 1,1,1-Trichloroethane (also referred to as Chlorothene) - Freon TF (1,1,2-Trichloro-1,2,2-trifluoroethane) Dichloromethane (also referred to as methylene chloride) and 1,2-dichloroethane (also referred to as ethylene dichloride) may be used for Plexiglass gluing operations. Batteries. instance, halogenated solvents such as methylene chloride and chloroform are more costly to dispose of than non-halogenated solvents such as hexane and xylene; therefore, halogenated solvent wastes should be kept separate from non-halogenated solvent wastes. Generic: F001. Waste of non-halogenated organic solvents : SW 323: Waste of halogenated organic solvents : SW 324: Waste of halogenated or unhalogenated non-aqueous distillation residues arising from organic solvents recovery process: SW 325: Uncured resin waste containing organic solvents or heavy metals including epoxy resin and phenolic resin : SW 326 Materials in this group are incompatible with strong . The term "Waste" should be included on the label, in addition to the chemical contents. • Flammableorganic solvents mixedwith halogenatedsolvents should be . Spent Non-Halogenated Solvent, Ethyl acetate methyl acetate Propylacetate Butanol Methanol Ethanol, Isopropyl alcohol, Propanol, Ethylene glycol, Glycol, Propylene glycol, . Complete F List. Three Types of Solvents: Oxygenated, Hydrocarbon, and Halogenated. Chlorobenzene 5. However, if the solvent contains any halogenated liquids (e.g. Dichloromethane". Except when waste is being added to or removed from a safety can containing hazardous waste, its lid needs to be closed at all times. They may react violently with aluminum. 2.3 NONHALOGENATED VOLATILE ORGANIC COMPOUNDS. This includes any metals. Approximately 99,000 metric tons of waste halogenated solvents from degreasing operations are generated each year (l). 3-Chloropropene 12. F004 The following spent non-halogenated solvents: cresols, cresylic acid, and nitrobenzene; all spent solvent mixtures/blends containing, before use, a total of 10% or more (by volume) of 1 or more of the above non-halogenated solvents or those solvents listed in F001, F002, and F005; and still bottoms from the recovery LIST OF TOXIC INDUSTRIAL WASTE COLLECTORS LICENSED UNDER THE ENVIRONMENTAL PUBLIC HEALTH (TOXIC INDUSTRIAL WASTE) REGULATIONS S/N Company Types of Toxic Industrial Waste Permitted to Collect . wipes and absorbent material contaminated with solvent, Waste rags, wipes and absorbent material contaminated with other chemical . Solvent Machine ID or Name Compliance Option(s) Selected* *State a control combination used, control system efficiency, or overall emission limit for batch vapor or inline machines.- Halogenated Solvents. Chloroethane 8. (T) F002 The following spent halogenated solvents: The present list is a harmonised list of wastes. "halogenated waste." As waste is added to container, add chemical Always keep hazardous waste containers capped and closed except when adding or removing material from the container. G703: Halogenated Organic Solvents- includes, but not limited to the following spent halogenated solvents as well as those listed in Priority Chemical List (PCL): Tetrachloroethylene; Trichloroethylene; Methylene chloride; 1, 1, 1 Trichloroethane; Carbon tetrachloride; Chlorobenzene; 1, 2, 2- Trichloroethane; chlorinated fluorocarbons if they contain a total of 10% or more (by volume) of one . The wastes regulated as listed chemical wastes are listed in 40 CFR sections 261.31 (F list), 261.32 (K list), 261.33 (P and U lists). Hazardous waste Hazard code ; Generic: F001: The following spent halogenated solvents used in degreasing: Tetrachloroethylene, trichloroethylene, methylene chloride, 1,1,1-trichloroethane, carbon tetrachloride, and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by . non- halogenated solvents or those solvents listed in F001, F002, or F004; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. Separate aqueous, halogenated and non-halogenated waste streams if possible. These solvents are not treatable in the present Industrial Waste Treatment Plants (IWTPs) and when exhausted, must be shipped to landfills for . DO NOT overfill the 5-gallon solvent containers beyond the 20 liter (5 gallon) mark. Aqueous waste containing cyanides (generally caustic) W110. Halogenated compounds contain any of the five electronegative elements namely, fluorine, chlorine, iodine, bromine and astatine. Do not intentionally mix halogenated solvents and/or solutes with non-halogenated solvents. F003. chlorinated) solvent w203 concentrated non-halogenated (e.g. Dibromomethane 15. Dangerous Waste Sources List Non-Specific Sources "F" List Dangerous Waste No. List all chemical contents on waste tag Oils () List any solvents, P 's or metal contamination Non-Halogenated Solvents, such as: - Acetone - Methanol -Acetonitrile Methyl ethyl ketone (MEK) Organic solvents: Halogenated and non-halogenated organic solvents may be mixed together in the same waste container. Chlorinated solvents Fluorocarbon solvents Brominated solvents Iodinated solvents Properties of some halogenated solvents Chlorinated solvents The common chlorinated solvents are Trichlorethylene (ClCH- Do not add excess solids or debris. 1. Contact the EH&S Environmental Management Facility, (858) 534-2753, if you want to pour other chemical constituents in the same waste . chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume) of one or more of the above halogenated solvents or those solvents listed in F002, F004, and F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. For example, a non-halogenated waste container should also contain the names of all types of solvents mixed in the container. Notice all four chemicals are . The F-list, found at 40 CFR section 261.31, identifies wastes from common manufacturing and industrial processes as hazardous. There are approximately 460,000 facilities dispersed throughout the country that use, halogenated solvents and generate these wastes (l). EPA Hazardous Waste Number: Hazardous Waste from non-specific sources: F001: The following spent halogenated solvents used in degreasing: Tetrachloroethylene, trichloroethylene, methylene chloride, 1,1,1- trichloroethane, carbon tetrachloride, and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume . chloroform, methyl iodide, etc. Chloromethane 11. Hazardous Waste Number Source; F001: The following spent halogenated solvents used in degreasing: Tetrachloroethylene, trichloroethylene, methylene chloride, 1,1,1-trichloroethane, carbon tetrachloride, and chlorinated fluorocarbons; all spent solvent mixtures/blends used in degreasing containing, before use, a total of ten percent or more (by volume) of one or more of the above halogenated . Solvents. Common examples include: Carbon Tetrachloride 4. Bromomethane 3. In this thesis, a bench-top semi- . F004 The following spent non-halogenated solvents: cresols, cresylic acid, and nitrobenzene; all spent solvent mixtures/blends containing, before use, a total of 10% or more (by volume) of 1 or more of the above non-halogenated solvents or those solvents listed in F001, F002, and F005; and still bottoms from the recovery Halogenated solvent waste generation was estimated at about 2,600 million ret 9 gallons/year, roughly 100 times greater than the 31 million gallons/year estimate for nonsolvent balogenated organic wastes provided by Westat.' 2-17 HALOGENATED and NON-HALOGENATED solvents have to be segregated into separate, labeled containers. This marks the first addition to the list since it was established as part of the 1990 Clean Air Act Amendments. F-list | 2 EPA Waste Code Hazardous waste Hazard code more of those solvents listed in F001, F002, F004, and F005; and still bottoms from the recovery of these spent solvents and spent solvent mixtures. We find that the probability that a facility is selected as the destination of an off-site shipment . A3160. The objective of the solvent separation is to keep the halogen content of the organic solvents for incineration below 1.0% by volume. Accurately list the bag's contents and chemical constituents on the hazardous waste tag. w202 co ncentrated halogenated (e.g. treatment in order to minimise environmental pollution during waste disposal. HALOGENATED SOLVENTS Halogenated solventis an organic solvent, molecules of which contain halogenic atoms: chlorine (Cl), fluorine (F) , bromine (Br) or iodine (I). Non-Halogenated Solvent Waste: This is the most common waste stream, consisting of solvents such as acetone, ethanol, methanol, ether, hexanes, ethyl acetate, and toluene. 2-Chloroethyl vinyl ether 9. Non-Halogenated solvent container provided by EH&S • Halogens include Chlorine,Fluorine,Bromine, andIodine halogenatedsolvent wasteis bulked in drums by EH&S for disposal. . 1. Sites where nonhalogenated VOCs may be found include burn pits, chemical manufacturing plants or disposal areas, contaminated marine sediments, disposal wells and leach fields, electroplating/metal finishing shops, firefighting training areas, hangars/aircraft maintenance areas, landfills and . The family of chemicals called "halogens" include bromine, chlorine, fluorine and iodine, among others. The NIH chemical waste contractors will provide 3 or 5 gallon plastic solvent safety cans (for flammable solvent mixtures), 3 or 5 gallon blue plastic carboys for liquid wastes and a 5 gallon plastic pail for gels and solid wastes. For non-halogenated and halogenated solvent waste this is 'ignitable'. The spent solvent listings in §261.31 are worded "The following spent halogenated/ non-halogenated solvents." which clearly designates only the listed solvents. Refer to the Appendix for a detail list of these wastes. Waste halogenated organic solvents. What Are Halogenated Solvents? It will be periodically reviewed on the basis of new knowledge and, in particular, of research results, and if necessary revised in accordance with Article 18 of Directive 75/442/EEC. The solvent waste will be burnt up. The nonhalogenated solvent waste stream is our most cost - effective disposal waste stream. All waste containers must be kept closed except when adding waste to the container. 2) Liquid, non-halogenated, organic solvents may be combined in a "non-halogenated waste" container. The low-molecular-weight materials (gases and liquids) are generally dangerously flammable. Chlorodibromomethane 7. nonhalogenated: [adjective] not treated or combined with a halogen : not halogenated. destroy halogenated hydrophobic organic compounds from soil. Rule History 12/03/2008 - Notice of Extension of Public Comment Period Industry and EPA hazardous waste No. 2-Chloro-1,3-butadiene 6. Non-halogenated solvents include methanol, acetone and xylene. list of waste codes and descriptions. Other inorganic liquid Waste halogenated or unhalogenated non-aqueous distillation residues arising from organic solvent recovery operations (A3170) Wastes arising from the production of aliphatic halogenated hydrocarbons (such as chloromethanes, dichloro-ethane, vinyl chloride, vinylidene chloride, allyl chloride and epichlorhydrin) F003. CiteSeerX - Document Details (Isaac Councill, Lee Giles, Pradeep Teregowda): Chlorinated hydrocarbons and petroleum distillates are presently used for cleaning, degreasing, and masking-wax removal at the five Air Force Air Logistics Commands (ALCs). The contents of the drum, including the recyclable waste, will be destroyed in an incinerator. The following spent non-halogenated solvents: Xylene, acetone, ethylacetate, ethyl benzene, ethyl ether, methyl isobutyl ketone, n-butylalcohol, cyclohexanone, and . Trans-1,4-Dichloro-2 - butene 16. Halogenated solvent waste also should read 'toxic'. If organic solvent waste meets the restrictions below, It is estimated that about 30,000 metric tons per year of halogenated hydrocarbons . Non -halogenated organic solvents ] isohutanol, pyridine, benzene, 2 -ethoxy 1 I ethanol, and 2-nitropropane and other non-halogenated organic solvents if they contain a total of 10Y'o or more (by volume) of one or more of these solvents before use; it also includes all still hottoms from rPcoveT of these solvents i -- I. ;md solvent mixi -. It is a liquid and corrodes steel (Type SAE 1020) at a rate greater than 6.35 mm (approximately 0.250 inch) per year. • Keep separatefrom non-halogenatedorganic solvents for solvent recovery. Non-Halogenated Waste (organic solvents that do not contain F, Cl, Br, or I) Acetone Acetonitrile Bis / Tris solutions Cyclohexane DAPI DMSO EDTA Ethyl Alcohol ≥24% Ethyl Ether Fluorescein Hematoxylin HEPES Hexanes Hybridization buffer (sodium dodecyl sulfate / sodium phosphate dibasic Halogenated Waste (any organic chemical that contains F, Cl, Br, or I) Segregate waste containers according to contents (flammable, corrosive, etc.) Heavy metal and other aqueous waste streams should be The following spent halogenated solvents used in degreasing: tetrachloroethylene, trichloroethylene, methylene chloride, 1,1,1-trichloroethane, carbon tetrachloride, and chlorinated fluorocarbons; all spent solvent mixtures/blends used in . Identify the compliance method or option selected for each machine. Halogenated (Yellow/Orange Carboys) Chloroform L Dichloromethane L Other Flammable Solvents Please list any other solvents below Other Information For office use only Gallons: Pounds: Tips on Keeping Accurate Inventory of Carboy Content • Put one person in charge of waste solvent collection and record keeping. Sources F001 The following spent halogenated solvents used in degreasing: Tetrachloroethylene, trichloroethylene, methylene chloride, 1,1,1-trichloroethane, carbon tetrachloride, and chlorinated fluorocarbons; all spent solvent "ANNEX List of wastes pursuant to Article 1(a) of Directive 75/442/EEC on waste and Article 1(4) of Directive 91/689/EEC on hazardous waste Introduction. A description of the hazard characteristics should also be on the label. Chemical waste in tubes Vials, conicals, etc… containing compatible wastes. 4. There are literally thousands of types of solvents available for purchase. Waste liquid mercury (metallic) W119. CiteSeerX - Document Details (Isaac Councill, Lee Giles, Pradeep Teregowda): In this paper, we estimate conditional logit models of generator's choice of waste management facilities (TSDFs) for shipments of halogenated solvent waste documented by the manifests filled out in California in 1995. halogenated solvents, or one or more of these non-halogenated solvents and a total of 10 percent or more by Because the processes generating these wastes can occur in different sectors of industry, the F list wastes are known as wastes from non-specific sources. Stat is a mainly substance-oriented aggregation of the waste types defined in the European List of Wastes (LoW) 2. The result is a 1:n-relationship between EWC-Stat and European List of Wastes which allows for the unambiguous conversion of the waste types classified according to the List of Wastes into the EWC-Stat waste categories. Hazardous waste. 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